相关实验视频
Updated: Jan 27, 2026

04:35
Preparation of Free-Surface Hyperbolic Water Vortices
Published on: July 28, 2023
3.8K
氧化物表面上的水:在Co3O4上的一个Triaqua表面协调综合体
George Yan1, Tobias Wähler2, Ralf Schuster2
1Department of Chemical and Biomolecular Engineering , University of California, Los Angeles , Los Angeles , California 90095 , United States.
Journal of the American Chemical Society
|March 22, 2019
概括
水与氧化物表面的相互作用揭示了新的水分结构. 这项研究有助于更好地了解催化和电催化中的金属氧化物表面.
科学领域:
- 表面科学
- 催化剂
- 计算化学
背景情况:
- 水与金属氧化物的相互作用对于异质催化和电催化至关重要.
- 了解表面结构是控制物质活动和稳定的关键.
研究的目的:
- 通过水与氧化物 (Co3O4) 表面相互作用而形成的结构图案.
- 描述金属氧化物表面的新型水分结构.
主要方法:
- 密度函数理论 (DFT) 的计算.
- 红外反射吸收光谱 (IRAS).
主要成果:
- 观察到三个主要结构:隔离的OD,与结合的OD/D2O,以及一个新的"半化"结构.
- 这种新型结构涉及表面CO2+离子与3个D2O分子结合,形成一个八面体协调的CO2+.
- 这种结构被认为是氧化物表面重组和溶解的中间体.
结论:
- 在Co3O4{111}表面上发现了新的水分结构.
- "半水化外"的结构为水氧化物相互作用提供了新的见解.
- 这些发现对理解和设计金属氧化物催化剂和电催化剂具有重要意义.
相关概念视频
Coordination Number and Geometry
19.0K
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
19.0K
Surface Tension and Surface Energy
3.2K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
3.2K
Coordination Compounds and Nomenclature
26.6K
In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
26.6K
Wood Surfacing
353
Wood surfacing is a critical finishing process designed to smoothen the wood surface, enhance its dimensional accuracy, and make handling safer. This process compensates for potential shrinkage during the seasoning phase by marginally increasing the wood dimensions before surfacing. It also helps correct some distortions that may occur as the wood dries.
The equipment used in the surfacing process is a plane equipped with rotating blades. This tool efficiently smoothens the wood surface and can...
The equipment used in the surfacing process is a plane equipped with rotating blades. This tool efficiently smoothens the wood surface and can...
353
Cell-surface Signaling
54.2K
Hormones—or any molecule that binds to a receptor, known as a ligand—that are lipid-insoluble (water-soluble) are not able to diffuse across the cell membrane. In order to be able to affect a cell without entering it, these hormones bind to receptors on the cell membrane. When a first messenger, a hormone, binds to a receptor, a signal cascade is set off, causing second messengers, proteins inside the cell, to become activated, resulting in downstream effects.
54.2K
Surface Tension, Capillary Action, and Viscosity
33.2K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
33.2K

