同质和异质共价有机框架的等级组装启用3D打印
Mingshi Zhang1, Longyu Li1, Qianming Lin1
1Department of Chemistry , Dartmouth College , 41 College Street , Hanover , New Hampshire 03755 , United States.
Journal of the American Chemical Society
|March 27, 2019
概括
研究人员开发了一种3D打印方法来创建先进的共价有机框架 (COF). 这种技术可以制造出复杂,多孔的COF结构,用于各种应用.
科学领域:
- 材料科学
- 聚合物化学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 是晶体多孔聚合物,通常以粉末或薄膜的形式合成.
- 现有的COF形式限制了它们的集成到复杂的三维 (3D) 架构中,用于高级应用.
研究的目的:
- 开发一种将COF整合到3D打印材料中的通用方法.
- 能够制造高精度和集成功能的复杂的3DCOF结构.
主要方法:
- 在水环境中与3D打印模板 (Pluronic F127) 组装 imine 聚合物,形成可打印的水凝.
- 控制多重凝结以实现剪切稀释和自我愈合的水凝特性.
- 在印刷后进行无形转化为晶体的热处理,从而产生3DCOF单体.
主要成果:
- 制造可3D打印的水凝,具有具有可取的质性质的胺或β-胺链接.
- 成功合成具有高晶度,等级多孔性,高表面积和强大的机械稳定性的3DCOF单体.
- 使用多种前体油墨,以高空间精度3D打印异构的双组件COF单体.
结论:
- 通过3D打印制造复杂的3D共价有机框架 (COF) 的多功能方法已经建立.
- 这种方法有助于将COF集成到具有互连接口的设备中,为先进的材料设计开辟了新的途径.
- 开发的技术允许在分子层面创建复杂的3D宏观结构和异质的COF集成.
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