通过 ZnCl2盐水电解质的反向双离子电池
Xianyong Wu1, Yunkai Xu1, Chong Zhang1
1Department of Chemistry , Oregon State University , Corvallis , Oregon 97331-4003 , United States.
Journal of the American Chemical Society
|March 29, 2019
概括
研究人员通过反向离子储存开发了一种反向双离子电池 (RDIB). 这种新的配置通过使用独特的电解质和电极设计来增强能量储存.
科学领域:
- 电化学
- 材料科学
- 能量储存
背景情况:
- 双离子电池 (DIB) 传统上储存阴极中的离子和阳极中的离子.
- 缺少阴极材料为先进的电池设计提供了潜力,但在水性电解质中面临挑战.
研究的目的:
- 引入和研究一个反向双离子电池 (RDIB) 配置.
- 展示一种在水性电解质中利用缺氧阴极材料的新方法.
- 通过战略电解质和电极设计提高双离子电池的性能.
主要方法:
- 使用微孔碳封装的铁素制造的离子插入阳极.
- 使用Zn插入的普鲁士蓝色阴极 (Zn3[Fe(CN) 6 2).
- 使用 30 m ZnCl2 "盐中的水" 电解质.
主要成果:
- RDIB配置成功地将阳极中的离子和阴极中的离子存储.
- "盐中的水"电解质减少了铁素溶解,并提高了电极电位.
- 与稀释电解质相比,实现了0. 35V的全电池扩张电压.
结论:
- RDIB为先进的电池化学提供了可行的配置.
- "盐中的水"电解质对于使RDIB在水系统中的性能至关重要.
- 这项工作提供了一个实用的解决方案,用于在储能器件中利用缺氧阴极.
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