自制组装的超分子球体是状的
Daniela A Wilson1, Katerina A Andreopoulou1, Mihai Peterca1,2
1Roy & Diana Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , Philadelphia , Pennsylvania 19104-6323 , United States.
Journal of the American Chemical Society
|April 2, 2019
概括
奇拉性树枝自组成单手超分子球体,形成一个宏观的奇拉性弗兰克-卡斯珀阶段. 这一发现质疑其他自组装软物质球体的性.
科学领域:
- 软物质物理
- 超分子化学
- 材料科学
背景情况:
- 弗兰克-卡斯珀相和液态准晶是由自组装的超分子球体产生的.
- 由于它们的同位体形状,这些球体通常是非圆形的.
- 然而,从螺旋状树枝状体堆中观察到奇拉的弗兰克-卡斯珀相.
研究的目的:
- 为了研究由状树枝形成的状超分子球体.
- 为了确定是否可以诱导在弗兰克-卡斯珀阶段的宏观性.
主要方法:
- 第二代和第三代双 propyl 树突的合成与性顶点组.
- 丹德隆的自我组装成类似球的球体.
- 自组织的超分子结构及其性.
主要成果:
- 一个奇拉性树突库成功地产生了单手奇拉性超分子球体.
- 最多480个圆状的树枝组装成球体,其摩尔质量最多为1.1 × 10^6 g/mol.
- 这些球体自组织成Pm3̅n立方相,表现出宏观的性.
结论:
- 在弗兰克-卡斯珀阶段内,由形圆形成的状球体可以表现出宏观的性.
- 这一发现挑战了同位素超分子球体中的无环性假设.
- 提出了关于其他软物质系统形成的3D相的基本问题.
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