通过连续障碍控制在高度连接的稀土金属有机框架中进行拓探索
Yutong Wang1, Liang Feng2, Weidong Fan1
1School of Materials Science and Engineering, College of Science , China University of Petroleum (East China) , Qingdao , Shandong 266580 , China.
Journal of the American Chemical Society
|April 6, 2019
概括
研究人员通过调整链接替代物开发了新的高度连接的稀土金属有机框架 (MOF). 这种硬质控制策略为先进的应用解锁了新的拓和复杂的多孔结构.
科学领域:
- 材料科学
- 化学学
- 晶体学
背景情况:
- 高度连接的金属有机框架 (MOF) 具有显著的潜力,但受到可用的拓和金属集群的限制.
- 开发用于新型MOF拓的策略对于扩展其应用至关重要.
研究的目的:
- 构建具有前所未有的拓的高度连接的稀土 (RE) MOF.
- 探索系统调节的链接器中的硬体阻碍对MOF结构和拓学的影响.
- 为设计复杂的多孔材料提供蓝图.
主要方法:
- 有系统调节的替代品的三极形连接器的故意选择.
- 稀土金属有机框架 (RE-MOF) 的建设.
- 使用混合连接器策略和分子模拟来控制硬体阻碍和预测结构.
主要成果:
- 使用C2v对称链接器和RE6集群形成新的 (3,9) -c分离拓.
- 通过将RE6集群调整为具有C1对称链接器的RE9集群,发现了一个 (3,3,18) -cytw拓.
- 合成基于RE9的MOF,使用可控硬体阻碍的混合链接器进行 (3,3,12) -c flg拓.
- 分子模拟证实了固体阻碍在决定MOF结构中的作用.
结论:
- 连接器替代物的系统化调是发现新MOF拓的有效策略.
- 可适应的稀土集群可以被利用来创建复杂的网络结构.
- 这种方法为设计具有定制性质的先进多孔材料提供了多功能平台.
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