化环电子接收膜中的高激发扩散系数
Sreelakshmi Chandrabose1,2, Kai Chen1,2, Alex J Barker3
1MacDiarmid Institute for Advanced Materials and Nanotechnology , Wellington 6010 , New Zealand.
Journal of the American Chemical Society
|April 10, 2019
概括
由分子设计驱动的有机光伏膜中的快速激子扩散显著提高了设备的性能. 这一突破可能会消除未来OPV细胞中复杂的纳米结构散体异构连接的需要.
科学领域:
- 材料科学
- 有机电子
- 太阳能发电
背景情况:
- 有机光伏 (OPV) 电池通常需要纳米结构的散体异质连接,因为激子扩散长度有限.
- 然而,这种纳米结构可能会阻碍有效的电荷收集并降低设备的整体性能.
研究的目的:
- 在与捐赠物质混合的新型化环电子受体中研究激子扩散动力学.
- 确定增强的激素扩散是否可以克服传统OPV形态的局限性并提高性能.
主要方法:
- 采用了温度依赖的超快速激素消灭测量方法来量化激素扩散.
- 分析了在有机膜中影响激子扩散的分子和包装因素.
主要成果:
- 解决了至少2×10-2cm/s的准无激活激子扩散系数,明显高于典型的有机半导体.
- 确定了分子刚性,平面结构,高染色体密度和低混乱为通过共振能传递增强激子扩散的关键因素.
- 取得的OPV性能超过了富勒烯基细胞.
结论:
- 由分子设计驱动的增强的三维激子扩散,通过促进电荷分离和运输,大大提高了OPV的性能.
- 优化的域结构和抑制的重组导致更高的填充因子.
- 在激素扩散方面进一步的改进可能会消除OPV中大量异质连接架构的必要性.
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