甲机械:合成,聚合和机械化学转化
Jinghui Yang1, Maggie Horst1, Joseph A H Romaniuk1
1Department of Chemistry , Stanford University , Stanford , California 94305 , United States.
Journal of the American Chemical Society
|April 11, 2019
概括
新的甲单体能够通过机械力转化为合材料的可扩展的聚合物. 这种机械化学方法提供了超越聚乙烯的新聚合物更容易的途径.
科学领域:
- 聚合物化学
- 材料科学
- 机械化学
背景情况:
- 聚拉德是一种多机电体,在机械力下重新排列,形成半导体聚乙烯.
- 开发新的机械孔系统对于制造应力材料至关重要.
研究的目的:
- 报告新的甲单体的可扩展合成.
- 研究这些新单体的聚合和机械化学转化.
- 通过机械化学方法产生聚乙烯以外的合聚合物.
主要方法:
- 可以扩展的甲单体合成.
- 环开转化聚合 (ROMP) 产生同聚合物和阻断共聚合物.
- 通过超声波进行机械化学转换以诱导键重组.
主要成果:
- 成功的可扩展的甲合成.
- 控制的聚乙烯同聚合物和低分散性的块共聚物合成.
- 不结合的聚乙烯的机械化学转化为结合的聚乙烯,转化率高达45%.
- 与以前的系统相比,一个更容易使用的合成路径的演示.
结论:
- 甲是一种新型的机械单体,具有更好的合成可访问性.
- 机械化学转化提供了产生合聚合物的有效方法.
- 这项工作将机械化学生成的合聚合物的范围扩大到聚乙烯之外.
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