通过循环盐单元作为节点定期定位的四功能远程前体的编程聚合物折叠
Kohei Kyoda1, Takuya Yamamoto1, Yasuyuki Tezuka1
1Department of Organic and Polymeric Materials , Tokyo Institute of Technology , O-okayama, Meguro-ku , Tokyo 152-8552 , Japan.
Journal of the American Chemical Society
|April 16, 2019
概括
这项研究证明了使用远程聚合物 (THF) 进行编程的聚合物折叠.不同的终端组反应性导致不同的聚合物折叠结构,形成手环或8形异构体.
科学领域:
- 聚合物化学
- 超分子化学
- 材料科学
背景情况:
- 具有功能终端组的远程聚合物对于受控聚合物架构至关重要.
- 编程的聚合物折叠提供了复杂的宏分子结构的途径.
- 了解功能组反应对折叠的影响是控制聚合物拓学的关键.
研究的目的:
- 通过使用远程聚合物 (THF) 演示可编程的聚合物折叠过程.
- 调查不同聚合物构成异构体的形成 (手环,8-, θ-形式).
- 将聚合物折叠结果与末端组和内部位置的化学反应性相关联.
主要方法:
- 与基盐组合成四功能,线性多基基.
- 通过环开放反应进行共价固定后的静电自组装.
- 使用1H NMR,MALDI-TOF质谱和SEC分析进行表征.
主要成果:
- 形成了双循环聚合物产品 (IIa和IIb),产生了组成性异构体.
- 聚合物Ia具有相应的结合组反应性,优先形成形同体.
- 聚合物Ib具有增强的N- 烯末端反应性,主要形成8型异构体.
结论:
- 可通过功能组的空间排列和化学反应来控制可编程的聚合物折叠.
- 特定的聚合物折叠异构体的形成是由聚合物的结构和化学特征指导的.
- 这项工作提供了可预测的折叠结构的聚合物设计的见解.
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