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通过将金属有机多面体隔离到狭窄的纳米空间来最大限度地提高光敏效率
Yao Jiang1, Jinhee Park2, Peng Tan1
1State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), College of Chemical Engineering , Nanjing Tech University , Nanjing 210009 , China.
Journal of the American Chemical Society
|April 16, 2019
在PubMed 上查看摘要
概括
在半孔 (MS) 中限制的光敏金属有机多面体 (PMOPs) 防止聚合,提高其效率. 这一突破最大限度地提高了对刺激有反应的客体吸附率,
科学领域:
- 材料科学
- 纳米技术
- 化学学
背景情况:
- 光响应金属有机多面体 (PMOPs) 提供可调节的功能和响应刺激的行为.
- 激活后散装PMOP的聚合损害了它们的光响应效率,并限制了应用.
研究的目的:
- 克服PMOP中的聚合问题,并最大限度地提高其光响应效率.
- 证明将PMOP限制在半孔 (MS) 中,以提高性能的好处.
主要方法:
- PMOPs被隔离并限制在半孔 (MS) 的纳米空间内.
- 使用紫外线/可见光照射实现了光响应组的可逆转换/晶体同质化.
- 在异构化之前和之后测量了小 () 和大 (明亮蓝色G) 分子的吸附行为.
主要成果:
- 在MS中限制PMOP表现出分散的结构,避免聚合.
- 光响应性客体吸附显示出显著的变化:为48. 2%,BBG为43. 9%.
- 这些结果远远超过了大量PMOP-1,分别显示只有11.2%和7.8%的变化.
结论:
- 在半孔中进行多面隔离有效地防止PMOP聚合,最大限度地提高光响应效率.
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