青衍生物的绿灯触发阶段过渡到可逆粘合剂
Zhen Wu1, Chendong Ji1, Xujie Zhao1
1State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing Laboratory of Biomedical Materials , Beijing University of Chemical Technology , Beijing 100029 , People's Republic of China.
Journal of the American Chemical Society
|April 17, 2019
概括
这项研究引入了一种可逆阿佐衍生粘合剂的新光热方法. 这些材料在绿色光线下从固体转化为液体,
科学领域:
- 材料科学
- 有机化学
- 摄影化学
背景情况:
- 亚衍生物通常使用光异构化进行相变,其自发逆转时间较慢.
- 对于先进的材料应用来说,开发快速反转的光诱导相位过渡至关重要.
研究的目的:
- 证明一种新的光热驱动的固态到液态相位过渡和在亚博衍生物中的快速逆转.
- 开发一种基于光诱导相变的可逆粘合剂的概念.
主要方法:
- 使用合适的替代性亚,使光热效应成为可能.
- 通过绿光辐射诱导固体到液体的转变.
- 观察由于释放热量的自发固化.
主要成果:
- 在亚博衍生物中实现光诱导的固体-液体过渡.
- 在2分钟内迅速,自发地固化.
- 获得了完全可逆的粘合力,强度与商业材料相美.
结论:
- 光热效应为阿佐衍生物的光诱导相变提供了新的途径.
- 这种方法可以制造出高效且快速可逆的粘合剂.
- 这些发现为使用有机化合物设计可逆粘合剂提供了一个新概念.
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