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分散分子网络中的强度,训练和杂交,以及生命的起源
Brian J Cafferty1, Albert S Y Wong1, Sergey N Semenov1
1Department of Chemistry and Chemical Biology , Harvard University 12 Oxford Street , Cambridge , Massachusetts 02138 , United States.
Journal of the American Chemical Society
|May 1, 2019
概括
反应物混合物的分子异质性可以维持化学网络中的复杂振荡,与同质混合物不同. 这一发现提供了关于生命起源和分子系统复杂性发展的见解.
科学领域:
- 化学学
- 生命起源的研究
- 系统化学
背景情况:
- 简单的化学反应自组成复杂的网络对于理解生命的起源至关重要.
- 分子和生物分子系统的复杂性从简单性增长仍然是一个重要的科学挑战.
研究的目的:
- 研究反应物组成的异质性如何影响散射分子网络的自我组装和稳定性.
- 确定分子异质性在维持化学反应网络中的振荡等复杂行为中的作用.
主要方法:
- 研究了一种微小的振荡性有机反应网络,
- 改变反应网络的组成,比较同质 (较少的反应物) 和异质 (多重反应物) 混合物.
- 操纵环境条件,例如空间速度,以评估网络的稳定性.
主要成果:
- 不同质的反应物混合物在胺基形成网络中存在持续的振荡,而同质的混合物则没有,尤其是在不断变化的环境条件下.
- 两个结构不同的反应物的混合物,单独无法振荡,在组合时表现出持续的振荡.
- 在研究的化学系统中,分子异质性被证明是促进而不是抑制复杂的动态行为.
结论:
- 分子组成的异质性是复杂和强大的化学网络的自组合的关键因素.
- 这些发现为生命起源出现的复杂性提供了潜在的机制.
- 这项研究强调了在设计和理解复杂分子系统时考虑反应物混合物多样性的重要性.
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