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相关概念视频

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

30.8K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
30.8K
Bonding in Metals02:32

Bonding in Metals

52.2K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
52.2K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

48.4K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
48.4K
Ionic Crystal Structures02:42

Ionic Crystal Structures

16.9K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.9K
Metallic Solids02:37

Metallic Solids

20.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Alkali Metals03:06

Alkali Metals

24.3K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.3K

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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一个单晶开放的金属有机框架

Yong-Sheng Wei1, Mei Zhang1, Mitsunori Kitta2

  • 1AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST) , Sakyo-ku, Kyoto 606-8501 , Japan.

Journal of the American Chemical Society
|May 3, 2019
PubMed
概括

研究人员开发了一种新型的单晶金属有机框架 (MOF) 囊, 这种囊式MOF可用于水分裂和气电池的高效多功能电催化.

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科学领域:

  • 材料科学
  • 纳米技术
  • 电化学

背景情况:

  • 微/纳米囊对于储存,催化和药物输送至关重要.
  • 传统囊由于其非/多晶壁而面临着加载和扩散的限制.

研究的目的:

  • 设计和合成一个具有固有的开口的新型单晶体金属有机框架 (MOF).
  • 从囊MOF制造一个化碳基框架,用于先进的电催化.

主要方法:

  • 晶体结构的转换以创建单晶囊MOF.
  • 化-化囊MOF和胺以形成含碳框架,并嵌入Fe-Ni化纳米粒子和碳纳米管.

主要成果:

  • 与现有的MOF相比,开封MOF的硫和负载能力更高.
  • 由添加的囊碳框架表现出高效的多功能电催化剂,用于氧气演变,气演变和氧气减少.

结论:

  • 新的囊MOF设计克服了传统微/纳米囊的扩散限制.
  • 制造的基碳基材料显示了整体水分裂和可充电Zn-空气电池的巨大潜力.