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通过可见光驱动的轴向螺旋分子开关实现的自组织螺旋超结构中的可逆循环极化反射
Hao Wang1, Hari Krishna Bisoyi1, Augustine M Urbas2
1Advanced Materials and Liquid Crystal Institute and Chemical Physics Interdisciplinary Program , Kent State University Kent , Ohio 44242 , United States.
Journal of the American Chemical Society
|May 4, 2019
概括
研究人员开发了一种可见光驱动的新型分子开关. 这种开关使液晶显示器的颜色变化可逆,为先进的光子设备铺平了道路.
科学领域:
- 材料科学
- 有机化学
- 摄影化学
背景情况:
- 开发具有可逆性能的光驱功能材料是一个关键的研究领域.
- 分子开关对于先进的光学和电子设备至关重要.
研究的目的:
- 合成和描述一种可见光驱动的新型分子开关.
- 在液晶中研究其光异构化行为和螺旋扭转功率 (HTP).
- 在可调节的光子显示器中展示其应用.
主要方法:
- 合成一种性分子开关,其中包含一个与轴性性支架相连的亚博基基基因.
- 使用可见光 (450 nm 和 530 nm) 的光异构化研究.
- 在胆固醇液晶宿主中测量螺旋扭力 (HTP).
- 光调色显示器的制造和测试
主要成果:
- 合成的分子作为一种性分子开关,通过可见光进行可逆的转向cis和 cis-to-trans光异构.
- 该开关具有高螺旋扭转功率 (HTP),在光异构化时发生显著变化.
- 在胆固醇液晶中实现了可见光谱的动态反射调整.
- 展示了发出红色,绿色和蓝色循环偏光的图案光显示器.
结论:
- 这项研究介绍了第一个通过C-C键直接将可见光驱动的亚博与轴向的分子开关.
- 由于可逆光异构化和高HTP,该材料在可调色彩显示器和光子设备中的应用具有前景.
- 开发的系统允许使用电场和机械力量在显示器上可逆隐藏和恢复信息.
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