含铜的碳原料用于生长超清洁石墨烯
Kaicheng Jia1, Jincan Zhang1,2, Li Lin1
1Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , People's Republic of China.
Journal of the American Chemical Society
|May 7, 2019
概括
研究人员开发了一种新的化学蒸汽沉积 (CVD) 方法, 这种无污染的石墨烯具有更好的光学和电气性能,
科学领域:
- 材料科学
- 纳米技术
- 化学工程
背景情况:
- 化学蒸汽沉积 (CVD) 对于大规模,高质量的石墨烯生产至关重要.
- CVD培养的石墨烯的表面污染限制了其在电子,光电子和膜应用中的使用.
研究的目的:
- 开发一种改进的气相反应,用于生长无污染的石墨烯.
- 为了提高CVD培养的石墨烯的表面清洁性和性能.
主要方法:
- 采用经过修改的高温CVD工艺,使用铜酸 (CuOAc) 2作为碳来源.
- 研究了气相铜含量增加抑制表面污染的作用.
- 分析了碳原料的分解及其对石墨烯质量的影响.
主要成果:
- 实现了大规模的超纯石墨烯生长,表面净度约为99%.
- 显著增强了所产生的石墨烯膜的光学和电气性能.
- 确定增加气相铜含量有效抑制污染形成.
结论:
- 使用铜酸的CVD方法提供了高质量,无污染的石墨烯的可行途径.
- 这种方法为控制石墨烯生长的气相反应机制提供了新的见解.
- 这种超清洁的石墨烯有可能用于先进的电子,光电子和膜应用.
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