微孔3D共价有机框架用于液态染色分离二烯同位素和乙烯
Jinjing Huang1, Xing Han1, Shi Yang1
1School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites , Shanghai Jiao Tong University , Shanghai 200240 , China.
Journal of the American Chemical Society
|May 16, 2019
概括
我们开发了微孔共价有机框架 (COFs),使用框架互透策略来有效分离C8基芳香异构体. 在通过液态染色学分离烯异构体和乙烯时,Salen-COFs表现出高性能.
科学领域:
- 材料科学
- 分离科学
- 纳米技术
背景情况:
- 微孔共价有机框架 (COF) 显示出小分子分离的希望.
- 设计和合成高效分离的COF仍然是一个挑战.
研究的目的:
- 开发微孔的COF,以有效分离C8芳分离体.
- 研究框架相互透和金属化对COF分离性能的影响.
主要方法:
- 通过希夫基凝结合成了四种3D盐和基COF.
- 使用框架透策略创建钻石形的开放框架.
- 使用高性能液态染色法 (HPLC) 来测试分离能力.
主要成果:
- 这四个COF是同结构的,具有7倍相互透的形框架和狭窄的管道.
- 盐酸COF表现出异同位素和乙的优异分离,达到基线分辨率.
- 不能实现高分辨率分离,这表明非协调的盐群的重要性.
- 盐酸COF对o- xylene具有很高的亲和力,可以在7分钟内快速分离.
结论:
- 框架相互透是设计微孔COF进行分离的有效策略.
- 不协调的salen基COF适用于芳香异构体的高性能液体色谱.
- 这项工作扩大了COF材料在异构分离中的应用潜力.
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