在Ternary Au (核心) -PtIr (外) 电催化剂上直接氧化乙醇
Zhixiu Liang1, Liang Song1, Shiqing Deng2
1Chemistry Division , Brookhaven National Laboratory , Upton , New York 11973 , United States.
Journal of the American Chemical Society
|May 28, 2019
概括
一种新的黄金-- (Au@PtIr) 核心催化剂通过促进C-C键裂变,显著增强了乙醇氧化反应 (EOR) 的活性. 这种设计促进了直接的12电子完全氧化路径,避免了CO中毒,以实现高效的电催化.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 合理的催化剂设计对于优化电催化反应至关重要.
- 了解金属和原子结构在基本步骤中的作用有助于催化剂的开发.
- 乙醇氧化反应 (EOR) 是性燃料电池的一个关键过程.
研究的目的:
- 开发一种新的三元 Au@PtIr核心催化剂,以提高 EOR.
- 阐明控制催化机制的结构活动关系.
- 研究促进完全乙醇氧化的途径,并最大限度地减少中毒物质.
主要方法:
- 一个三元 Au@PtIr核心催化剂的合成.
- 在性溶液中的电催化性能评估.
- 在位射线反射吸收光谱 (IRRAS) 分析催化剂.
- 与双金属子集 (Au@Pt,PtIr合金) 和合金催化剂的比较.
主要成果:
- 与AuPtIr合金相比,Au@PtIr催化剂的活性增强了6个级别.
- 单原子阶段和AU诱导的PtIr拉伸力有助于C-C键分裂.
- 在低电位上促进脱,使12电子直接氧化.
- 实现了低启动电位 (0.3 V) 和高峰电流 (8.3 A mg-1).
结论:
- Au核心和PtIr外的协同效应是提高EOR性能的关键.
- 在最初阶段的C-C键分裂激活了直接的全氧化路径,避免了CO中毒.
- Au@PtIr核心外催化剂代表了有效乙醇电氧化的重大进步.
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