相关实验视频
Updated: Jan 24, 2026

08:14
Ammonia Synthesis at Low Pressure
Published on: August 23, 2017
27.3K
在基于石墨烯的催化剂上高效和选择性地产生氨和
Lan Hui1, Yurui Xue1, Huidi Yu1
1Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190 , People's Republic of China.
Journal of the American Chemical Society
|June 1, 2019
概括
研究人员开发了一种新型的双功能原子催化剂 (AC),在石墨烯上使用零价,以有效地产生氨和. 这一突破为新一代高度选择性和活跃的催化剂提供了机会.
科学领域:
- 催化剂
- 材料科学
- 电化学
背景情况:
- 零价原子催化剂 (AC) 具有独特的特性和稳定性.
- 开发高效和选择性的降解和演变的催化剂至关重要.
研究的目的:
- 合成和描述一种用于同时产生氨和的新型双功能原子催化剂 (AC).
- 研究在石墨烯 (Mo0/GDY) 上分散的零价原子的催化性能.
主要方法:
- 容易和可扩展的Mo0 /GDY原子催化剂的高Mo含量 (高达7.5 wt %).
- 在水溶液中对降解反应 (NRR) 和演化反应 (HER) 进行电化学试验.
主要成果:
- 在室温和压力下,Mo0/GDY催化剂对NRR和HER都表现出极好的选择性和活性.
- 这代表了第一台能够高效和选择性地产生氨和的双功能交流机.
- 催化剂的结构已定义,其催化过程已被充分理解.
结论:
- 开发的Mo0/GDY原子催化剂是可持续化学生产的有前途的双功能材料.
- 这项工作为下一代高效和选择性原子催化剂奠定了基础.
- 催化剂的性能和已知的机制为实际应用铺平了道路.
相关概念视频
Hydrogen Bonds
131.8K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
131.8K
Hydrogen Bonds
13.5K
A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
13.5K
Preparation of Amines: Alkylation of Ammonia and Amines
4.6K
Alkylation is one of the methods used to prepare amines. Direct alkylation of ammonia or a primary amine with an alkyl halide gives polyalkylated amines along with a quaternary ammonium salt through successive SN2 reactions. This process of making the quaternary salt through the direct alkylation method is called exhaustive alkylation.
Each alkylation step makes the nitrogen center more nucleophilic, which triggers successive alkylations until a quaternary ammonium salt is formed. Considering...
Each alkylation step makes the nitrogen center more nucleophilic, which triggers successive alkylations until a quaternary ammonium salt is formed. Considering...
4.6K
What is Natural Selection?
126.3K
Natural selection is an evolutionary process in which individuals with survival-promoting traits reproduce at higher rates. These favorable traits become more common within a population or species. Naturally selected traits initially arise via random genetic mutations. In order for selection to occur, there must be variation within a population, the trait controlling the variation must be heritable, and there must be an evolutionary advantage for variation in the trait.
126.3K
Lewis Acids and Bases
48.2K
In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to donate a pair of electrons and form a coordinate covalent bond.
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
48.2K
Acids, Bases and Neutralization Reactions
63.6K
An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to numerous natural and technological processes, ranging from the chemical transformations within cells or lakes and oceans to the industrial-scale production of fertilizers, pharmaceuticals, and other substances essential to the society.
63.6K

