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相关概念视频

Metal-Ligand Bonds02:51

Metal-Ligand Bonds

24.1K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.1K
Bond Energies and Bond Lengths02:49

Bond Energies and Bond Lengths

31.3K
Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it.
31.3K
Peptide Bonds02:43

Peptide Bonds

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A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
82.5K
Bonding in Metals02:32

Bonding in Metals

52.1K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Ionic Bonds00:42

Ionic Bonds

129.5K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Covalent Bonds01:29

Covalent Bonds

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Overview
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相关实验视频

Updated: Jan 23, 2026

Residue-Free Fabrication of van der Waals Heterostructures of Two-Dimensional Materials
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Residue-Free Fabrication of van der Waals Heterostructures of Two-Dimensional Materials

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在2D捐赠-接受异构中结合

Adam H Woomer, Daniel L Druffel, Jack D Sundberg

    Journal of the American Chemical Society
    |June 13, 2019
    PubMed
    概括

    研究人员发现了一种新方法,通过将电子捐赠电子与其他二维材料堆叠来控制二维材料之间的距离. 这样可以创造出具有可调节性质的新型准键,从而实现先进的材料设计.

    科学领域:

    • 材料科学
    • 凝聚物质物理学
    • 纳米技术

    背景情况:

    • 控制原子距离对于设计新材料至关重要.
    • 在堆叠的二维材料中精确管理层间距离是一个重大挑战.

    研究的目的:

    • 研究将电子与其他二维材料堆叠在一起以控制层间距离的可能性.
    • 探索由此产生的供体-接受体异构结构的特性和应用.

    主要方法:

    • 使用第一原理计算来建模和分析二维材料的堆叠.
    • 这项研究利用了分子轨道理论的概念来理解结合特性.

    主要成果:

    • 将电子与其他二维材料堆叠在一起,可以精确控制层间距离,从而产生准键.
    • 这些准键表现出范德瓦尔斯相互作用和化学键之间的中间特性,具有可调节的极性和强度.
    • 已证明的应用包括超滑性,超低功率和增强离子电池性能.

    结论:

    • 由电子形成的捐赠-接受异构结构为材料设计提供了一种新的途径.
    • 可调整的准债券代表了一类具有重大技术潜力的新互动.

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  • 这些发现为开发具有定制性质的先进二维材料打开了道路.