原子分散的Fe3+位点催化有效的CO2电还原到CO
Jun Gu1, Chia-Shuo Hsu2, Lichen Bai1
1Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-LSCI, BCH 3305, Lausanne CH 1015, Switzerland.
概括
这项研究引入了一种新的基于铁的催化剂,用于有效地将二氧化碳 (CO2) 转化为一氧化碳 (CO). 单原子铁催化剂在低超电位下达到高活性,优于贵金属替代品.
科学领域:
- 电化学
- 材料科学
- 催化剂
背景情况:
- 黄金纳米材料是二氧化碳转化为二氧化碳的最活跃的电催化剂.
- 非贵金属催化剂对这种反应的活性有限.
研究的目的:
- 开发一种高活性且具有成本效益的二氧化碳电解催化剂.
- 研究单原子铁位点对二氧化碳转化成二氧化碳的性能.
主要方法:
- 电化学测试以测量催化活性和过量的潜能.
- 操作X射线吸收光谱,以确定活性点和氧化状态.
- 电化学数据分析以了解反应机制.
主要成果:
- 一个具有分散单原子铁位点的催化剂在80mV的超电位下实现了CO的产生.
- 在340mV的超电位下,部分电流密度达到94mA/cm2.
- 被确定为与碳支器上聚酸协调的离散Fe3+离子的活性位点,保持+3氧化状态.
结论:
- 在碳支中与N原子协调的单原子Fe3+位点表现出对CO2转化为CO的优异电催化活性.
- 与Fe2+位点相比,增强的活性归因于更快的CO2吸附和较弱的CO2吸附.
- 这种催化剂为黄金基催化剂提供了一个有前途的非贵金属替代品.
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