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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
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Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
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Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
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开发单质和寡质循环基流电池可溶性模型

Sophia G Robinson1,2, Yichao Yan3,2, Koen H Hendriks2

  • 1Department of Chemistry , University of Utah , 315 South 1400 East , Salt Lake City , Utah 84112 , United States.

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PubMed
概括

为非水性氧化还原流电池设计高可溶性有机分子至关重要. 这项研究开发了一种预测模型,用于三甲基氨基) cyclopropenium (CP) 衍生物,识别出具有1M以上在乙中溶解度的新化合物.

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科学领域:

  • 电化学
  • 材料科学
  • 有机化学

背景情况:

  • 氧化还原活性有机分子的高可溶性对于非水性氧化还原流电池 (NFRB) 是非常重要的.
  • 对非水溶性的预测方法是必要的,以加速发现合适的分子结构.
  • 三基氨基) 环基 (CP) 分离物是NFRB的一类有前途的化合物.

研究的目的:

  • 开发一种工作流程,用于参数化和预测CP基的可溶性.
  • 在相关电池电解质中识别具有高溶解性的新型CP衍生物.

主要方法:

  • 在单体CP物种上训练的统计模型的开发.
  • 对各种 CP 衍生物进行参数化和可溶性预测.
  • 在乙中进行电化学循环稳定性测试.

主要成果:

  • 已经成功开发了CP基解溶性的预测模型.
  • 新的单体和二体CP衍生物在所有氧化还原状态中可溶度超过1M.
  • 在没有支持电解质的1M度下,最易溶解的CP单体表现出高电化学稳定性.

结论:

  • 开发的工作流程有效地预测了形状灵活的CP基的可溶性.
  • 这项工作确定了高性能NFRB的有前途的CP衍生品.
  • 这些发现为有机电解质用于储能的合理设计铺平了道路.