在丰富的多层氧化物中缺乏工程 Li1.098Mn0.533Ni0.113Co0.138O2用于高稳定性阴极
Pengfei Liu1, Hong Zhang2, Wei He1
1State Key Lab of Physical Chemistry of Solid Surface, Collaborative Innovation Center of Chemistry for Energy Materials, College of Materials , Xiamen University , Xiamen 361005 , China.
Journal of the American Chemical Society
|June 18, 2019
概括
减少富含的层氧化物中的含量可以提高阴极性能. 这种缺乏的方法提高了先进电池的动力学,稳定性和速率能力.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 富含的层氧化物为储能应用提供了高的特定容量.
- 挑战包括这些材料的低动力,电压衰减和容量衰减.
研究的目的:
- 通过缺乏策略解决丰富的层氧化物的性能限制.
- 研究空位对正极材料性能的影响.
主要方法:
- 合成了一种缺乏Li的阴极材料:Li1.098Mn0.533Ni0.113Co0.138O2.
- 研究了修改后的阴极的结构和电化学特性.
主要成果:
- 实现了改善的初始库伦比效率和优异的速度能力.
- 经证实压制电压衰减和卓越的长期循环稳定性 (在1°C下经过500个循环后保持93. 1%).
- 通过空隙引起的表面螺旋涂层和涂层.
结论:
- 缺乏的方法有效地提高了丰富的层氧化物阴极的电化学性能.
- 空缺是开发电池高性能阴极材料的一个有希望的策略.
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