螺旋范德瓦尔斯晶体与离散的埃舍尔比扭曲
Yin Liu1,2, Jie Wang3, Sujung Kim1,4
1Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Nature
|June 21, 2019
概括
研究人员展示了一种创新的自下而上的方法来创建扭曲的范德瓦尔斯结构. 这种技术利用来自螺丝位的埃舍尔比扭曲来控制扭曲拓和定制材料属性.
科学领域:
- 材料科学
- 凝聚物质物理学
- 纳米技术
背景情况:
- 操纵范德瓦尔斯 (vdW) 结构的扭曲拓为调整它们的电气和光学特性提供了强大的途径.
- 扭曲角度通过层间合显著影响电子状态,激子和声子,导致异国情调的行为.
- 现有的转移堆叠方法不适合具有强度层间结合的材料.
研究的目的:
- 开发一个简单的自下而上的增长方法来创造扭曲的范德瓦尔斯结构.
- 调查埃舍尔比扭转和螺杆脱位在形成这些结构中的作用.
- 为了证明对扭曲拓的控制,以定制材料属性.
主要方法:
- 在成长中的纳米电线中引入轴向螺丝脱位,以诱导连续扭转.
- 在基板上利用扭曲的纳米线的辐射增长.
- 控制结构的辐射尺寸以量身定制扭转拓.
主要成果:
- 证明了埃舍尔比扭曲驱动扭曲VDW结构的形成,从纳米尺度到中等尺度.
- 在纳米结构中实现连续扭转,扭转速率由纳米线半径决定.
- 通过离散的扭转跳跃观察到弹性能量减少,形成具有尖接口的纳米板螺旋组件.
- 通过控制辐射结构大小来展示可定制的扭曲拓.
结论:
- 埃舍尔比扭曲提供了一个可行的自下而上合成扭曲范德瓦尔斯结构的机制.
- 这种方法克服了强固结合材料的转移堆叠的局限性.
- 控制扭曲拓的能力为设计先进的电子和光学材料开辟了新的途径.
相关概念视频
Van der Waals Interactions
70.9K
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
70.9K
Van der Waals Equation
6.2K
The ideal gas law is an approximation that works well at high temperatures and low pressures. The van der Waals equation of state (named after the Dutch physicist Johannes van der Waals, 1837−1923) improves it by considering two factors.
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
6.2K
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
38.9K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws.
38.9K
Noncovalent Attractions in Biomolecules
64.3K
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
64.3K
Angle of Twist: Problem Solving
764
An electric motor applies a torque of 700 N·m to an aluminum shaft, triggering a stable rotation. Two pulleys, B and C, are subjected to torques of 300 N·m and 400 N·m, respectively. The modulus of rigidity is provided as 25 GPa. With the knowledge of the length and diameter of each segment, the twist angle between the two pulleys can be computed. First, a section cut is made between pulleys B and C, and the cut cross-section is analyzed using a free-body diagram. Given that the torque...
764
Van de Graaff Generator
2.4K
Van de Graaff generators (or Van de Graaffs) are devices used to demonstrate high voltage due to static electricity that can also be used for research. Robert Van de Graaff first built one in 1931 (based on original suggestions by Lord Kelvin) for use in nuclear physics research.
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
2.4K


