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相关概念视频

Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

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The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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Electronic Structure of Atoms02:28

Electronic Structure of Atoms

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An atom comprises protons and neutrons, which are contained inside the dense, central core called the nucleus, with electrons present around the nucleus. Taking into account the wave–particle duality of electrons and the uncertainty in position around the nucleus, quantum mechanics provides a more accurate model for the atomic structure. It describes atomic orbitals as the regions around the nucleus where electrons of discrete energy exist, characterized by four quantum...
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Atomic Structure01:33

Atomic Structure

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Overview
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Atomic Orbitals02:44

Atomic Orbitals

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An atomic orbital represents the three-dimensional regions in an atom where an electron has the highest probability to reside. The radial distribution function indicates the total probability of finding an electron within the thin shell at a distance r from the nucleus. The atomic orbitals have distinct shapes which are determined by l, the angular momentum quantum number. The orbitals are often drawn with a boundary surface, enclosing densest regions of the cloud.
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Atomic Radii and Effective Nuclear Charge03:08

Atomic Radii and Effective Nuclear Charge

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The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
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Electron Orbital Model01:18

Electron Orbital Model

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Orbitals are the areas outside of the atomic nucleus where electrons are most likely to reside. They are characterized by different energy levels, shapes, and three-dimensional orientations. The location of electrons is described most generally by a shell or principal energy level, then by a subshell within each shell, and finally, by individual orbitals found within the subshells.
The first shell is closest to the nucleus, and it has only one subshell with a single spherical orbital called the...
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Atom Probe Tomography Analysis of Exsolved Mineral Phases
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使用原子电子断层扫描四维观察晶体核

Jihan Zhou1,2, Yongsoo Yang1,2,3, Yao Yang1,2

  • 1Department of Physics and Astronomy, University of California, Los Angeles, CA, USA.

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|June 28, 2019
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概括

原子电子断层扫描揭示了早期原子核的4D原子结构和动态. 这一突破为原子核形成过程和相变提供了新的见解.

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科学领域:

  • 材料科学
  • 纳米科学
  • 凝聚物质物理学
  • 化学学

背景情况:

  • 核化对于各种物理和生物过程至关重要,包括结晶和疾病形成.
  • 在原子层面研究早期核形成具有实验性挑战性.
  • 之前的方法缺乏确定新生原子核的3D原子结构和动态的分辨率.

研究的目的:

  • 用原子分辨率在四个维度 (4D) 中研究早期核化.
  • 在形成和演化过程中确定核的原子结构和动力学.
  • 为完善核化理论提供实验证据.

主要方法:

  • 使用原子电子断层扫描来实现4D原子分辨率成像.
  • 使用FePt纳米粒子作为核化研究的模型系统.
  • 通过Pt核的分子动力学模拟证实了这些发现.

主要成果:

  • 早期的原子核呈现出不规则的形状,其中1至3个原子的核心呈现出最大的秩序.
  • 顺序参数梯度指向从核到它的边界.
  • 观察并捕捉核的动态行为,包括生长,溶解,合并和分裂.

结论:

  • 原子电子断层扫描提供前所未有的4D原子分辨率.
  • 早期核的动力学由顺序参数分布和梯度来决定.
  • 古典核化理论需要修订来描述原子规模的核化过程.
  • 这种方法可以研究各种现象,如相位过渡和原子扩散.