由混合溶液中的两个单晶相接形成的有机异构结
Huanbin Li1,2, Jiake Wu1,2, Kohtaro Takahashi3
1MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering , Zhejiang University , Hangzhou 310027 , China.
Journal of the American Chemical Society
|June 28, 2019
概括
研究人员开发了一种使用单晶的新方法来创建高质量的有机异质连接. 这种技术可以精确控制分子包装,从而提高有机电子设备的性能.
科学领域:
- 材料科学
- 有机电子
- 晶体学
背景情况:
- 有机异质连接是有机电子中的关键组件.
- 在异质连接中实现有序的分子包装是具有挑战性的.
- 从有机半导体中形成单晶异质连接是很困难的.
研究的目的:
- 从接口单晶体创建有机异质连接的方法.
- 从溶液滴中了解有机半导体的结晶机制.
- 研究由此产生的单晶异质连接的电荷传输特性.
主要方法:
- 六个有机半导体从各种基板上的混合溶液滴中结晶.
- 在空气-溶液和溶液-基板接口上的结晶机制的观察和分析.
- 使用形成的异质连接器制造和表征有机场效应晶体管 (OFET).
主要成果:
- 根据界面偏好 (上或下) 确定了两个不同的结晶机制.
- 证明结晶偏好可以通过基质选择调节,这表明基质与半导体相互作用的重要性.
- 成功形成双层单晶,产生具有双极电荷传输的有机异质连接.
- 实现了高电子流动性1.90 cm2 V1 sâ1和孔流动性1.02 cm2 V1 sâ1.
结论:
- 阐明界面结晶事件是控制有机异质连接形成的关键.
- 开发的方法允许溶液生长的有机单晶异质连接具有出色的电荷传输特性.
- 这项工作为先进的有机电子设备铺平了道路,
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