在玻璃聚合物中实现室温机色激活:螺旋聚碳酸的合成和表征
Yuval Vidavsky, Steven J Yang, Brooks A Abel
1Schulich Faculty of Chemistry , Technion - Israel Institute of Technology , Haifa 3200003 , Israel.
Journal of the American Chemical Society
|June 28, 2019
概括
这项研究证明了高性能聚碳酸塑料的室温机色激活. 这一突破使得结构材料的早期损坏可以被检测,从而提高了安全性和耐用性.
科学领域:
- 材料科学
- 聚合物化学
- 智能材料
背景情况:
- 机色聚合物提供了通过力响应分子 (机电孔) 检测损伤的潜力.
- 之前在结构性塑料中的应用是有限的,因为颜色变化之前的脆性故障.
研究的目的:
- 在高玻璃过渡温度 (Tg) 中实现室温机色激活
- 开发有效的方法将机色功能纳入结构性塑料.
主要方法:
- 通过在聚碳酸盐中将二氧化作为共体聚合,增加了机色功能.
- 对压力,变形和时间的机色反应进行了研究.
- 展示了一种新型的层状方法,用于在不散散的情况下整合机色功能.
主要成果:
- 在保碳酸盐中实现室温机色激活,同时保持其热力学性能.
- 了解负载历史如何影响聚合物链中的应力积累.
- 成功展示了一种有效的机色材料集成的层状材料方法.
结论:
- 在聚碳酸等结构聚合物中,室温机色激活是可行的.
- 新的制备和加工方法推动了机色智能材料的应用.
- 这项工作为工程塑料中的实际损坏预警系统铺平了道路.
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