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Updated: Jan 22, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

Published on: August 23, 2018

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在olefin转化中将活动与可访问性整合起来:一个前所未有的反应性鲁-印尼利丁催化剂

Daniel L Nascimento1, Anna Gawin2, Rafał Gawin2

  • 1Center for Catalysis Research and Innovation, and Department of Chemistry and Biomolecular Sciences , University of Ottawa , Ottawa , Ontario K1N 6N5 , Canada.

Journal of the American Chemical Society
|June 29, 2019
PubMed
概括

一个新的二元性内尼利丁复合物 (Ru-1) 提供了高度活跃的烯转化催化剂的可扩展合成. 这一突破使高反应性与实际生产相结合,克服了以前的印尼利丁催化剂的局限性.

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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Enols are a class of compounds where a hydroxyl group is attached to a carbon–carbon double bond, which implies that it is a vinyl alcohol. A carbonyl compound with an α hydrogen undergoes keto–enol tautomerism and remains in equilibrium with its tautomer, the enol form. Usually, the keto tautomer is present in a higher concentration than the enol tautomer due to the higher bond energy of C=O compared to C=C. Moreover, the direction of the keto–enol equilibrium is...
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