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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Cooperative allosteric transitions can occur in multimeric proteins, where each subunit of the protein has its own ligand-binding site. When a ligand binds to any of these subunits, it triggers a conformational change that affects the binding sites in the other subunits; this can change the affinity of the other sites for their respective ligands. The ability of the protein to change the shape of its binding site is attributed to the presence of a mix of flexible and stable segments in the...
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Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
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In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
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Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
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The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
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在SmMn2O5表面使用合作格子氧化还原剂进行稳定和活性氧化催化

Yongping Zheng1, Sampreetha Thampy1, Nickolas Ashburn1

  • 1Department of Materials Science and Engineering , University of Texas at Dallas , Richardson , Texas 75080 , United States.

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|June 29, 2019
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概括

研究人员通过在SmMn2O5聚氧化物中利用合作晶格氧氧还原剂来克服催化剂设计的挑战. 这种方法可以实现氧化反应的高热稳定性和催化活性.

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科学领域:

  • 材料科学
  • 催化剂
  • 表面化学

背景情况:

  • 在恶劣条件下开发完整氧化反应的氧化催化剂受到格子氧结合能和氧化活性之间的反向相关性限制.
  • 较强的氧结合确保了表面稳定性,但降低了催化活性,而较弱的结合增强了活性,但损害了稳定性.

研究的目的:

  • 调查氧化催化剂中可否绕过晶格氧结合能和氧化活性之间的矛盾相关性.
  • 探索合作晶格氧氧还原机制的潜力,以设计稳定和活跃的氧化催化剂.

主要方法:

  • 使用氧化 (NO) 催化氧化作为研究氧化催化剂的模型反应.
  • 使用现场光谱技术和理论计算 (隐含) 调查了SmMn2O5的表面反应机制.

主要成果:

  • 证明SmMn2O5聚氧化物上的合作晶格氧化还原成功地避免了结合能和活性之间的典型权衡.
  • 确定了一种反应途径,涉及桥接和单酸盐中间体,氧气空缺和合作晶格氧气参与.
  • 展示了催化剂在苛刻条件下保持稳定和活跃的表面结构的能力.

结论:

  • 合作晶格氧氧还原为克服设计氧化催化剂完全氧化的基本局限性提供了一种可行的策略.
  • 这些发现为反应机制提供了关键的见解,使先进的氧化催化剂能够合理设计,具有增强的O2激活,高氧活性和卓越的热稳定性.