界面能量景观对ZnPc/MoS2界面的光诱导电荷产生的影响
Tika R Kafle1, Bhupal Kattel1, Peng Yao1,2
1Department of Physics and Astronomy , University of Kansas , Lawrence , Kansas 66045 , United States.
Journal of the American Chemical Society
|July 2, 2019
概括
有机/MoS2接口的电荷转移激子的行为不同. 不仅仅是带线对齐, 潜在能量格局也决定了电荷分离为自由载体.
科学领域:
- 材料科学
- 物理化学
- 表面科学
背景情况:
- 单层过渡金属二化物 (TMDC) 晶体与有机分子形成异构结构.
- 超快速的电荷转移 (CT) 发生在有机/TMDC接口上,但激子分离为自由载体尚未完全理解.
研究的目的:
- 调查甲 (ZnPc) /MoS2接口中的电荷转移和激子动态.
- 了解有利于电荷分离与重组的条件.
主要方法:
- 时间分辨率和稳定状态光辐射光谱.
- 研究了ZnPc/单层MoS2和ZnPc/散装MoS2的接口.
主要成果:
- 这两种接口都显示了II型带调整和超快的电荷转移 (<100 fs).
- ZnPc/单层MoS2可促进激素分裂为自由载体.
- 由于带曲差异,ZnPc/散装MoS2表现出反向电子转移,在ZnPc中形成三重激子.
结论:
- 潜在能量环境对接口电荷分离有很大的影响.
- 仅仅对能量水平的调整不足以预测有机/TMDC接口的免费电荷产生.
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