可溶液加工的超原子薄膜
Jingjing Yang1, Boyuan Zhang1, Alexander D Christodoulides2
1Department of Chemistry , Columbia University , New York , New York 10027 , United States.
Journal of the American Chemical Society
|July 2, 2019
概括
研究人员从纳米级集群开发了新的离子超原子材料. 这些无形薄膜具有可调节的特性,如高导电性和透明度,与传统的晶体不同,为先进的电子和热电器件铺平了道路.
科学领域:
- 材料科学
- 纳米技术
- 固态化学
背景情况:
- 原子精确的纳米级集群可以通过静电相互作用形成晶体离子固体.
- 这些集群的结晶成有序结构限制了它们的潜在应用.
研究的目的:
- 用灵活的侧链研究纳米级集群中的静电相互作用的挫折.
- 为电子和热电应用开发具有可调节性质的新型无形超原子材料.
主要方法:
- 合成了长,灵活的侧链以阻止静电相互作用的大纳米级集群.
- 溶液处理这些集群成无形和均的薄膜.
- 描述了由此产生的超原子材料的电,热和光学特性.
主要成果:
- 获得离子超原子材料, 保持无形, 防止结晶.
- 具有非常高的电导率 (高达300S/m) 的可调配组合.
- 观察到极低的导热率 (0.05 W/m·K) 和高的光学透明度 (高达92%).
- 有希望的,未优化的ZT值为0.02的薄膜热电材料.
结论:
- 通过控制集群间相互作用,可以将离子超原子材料加工成无形薄膜.
- 这些无形材料表现出在晶体对应物中不存在的独特特性.
- 超原子薄膜是电子和热电设备的有前途的新材料.
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