可逆聚合物链修饰:聚乳的环开闭
Seunghwan Moon1, Koichiro Masada1, Kyoko Nozaki1
1Department of Chemistry and Biotechnology, Graduate School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
Journal of the American Chemical Society
|July 2, 2019
概括
研究人员在二氧化碳和丁共聚物中实现了可逆的聚合物修饰. 这一过程涉及开启和重新关闭聚合物链结构,而不会改变分子重量或整体聚合物特性.
科学领域:
- 聚合物化学
- 有机化学
- 材料科学
背景情况:
- 二氧化碳 (CO2) 和丁的共聚物为新材料的开发提供了潜力.
- 对于动态材料应用,可逆聚合物修饰是可取的.
- 控制聚合物的结构变化而不会降解是一个关键挑战.
研究的目的:
- 开发一种可逆聚合物修饰策略,用于CO2-丁共聚物.
- 调查修改过程的结构变化和可逆性.
- 在可逆改造过程中确认聚合物完整性.
主要方法:
- 在共聚物中的乳部分的水解和氨解.
- 开放的聚合物结构的热诱导环闭.
- 使用核磁共振 (NMR) 和矩阵辅助激光吸附/离子飞行时间 (MALDI-TOF) 质谱的表征.
- 尺寸排除色谱 (SEC) 用于评估分子重量和多分散性.
主要成果:
- 通过水解和氨解成功打开乳部分.
- 只有通过加热,没有额外的试剂或溶剂才能实现有效的环闭.
- 核磁共振,MALDI-TOF和SEC分析证实了聚合物结构的保留,分子重量和多分散性.
- 证明了聚合物修饰过程的可逆性.
结论:
- 对CO2-丁烯共聚物实现了新的无试剂可逆聚合物修饰.
- 改造过程保留了聚合物的基本结构和分子特性.
- 这种可逆变化为开发可适应和可回收的聚合物材料开辟了道路.
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