碳酸连接共价有机框架的多级固态有机合成
Steven J Lyle1, Thomas M Osborn Popp1,2, Peter J Waller1
1Department of Chemistry, University of California-Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory , Kavli Energy NanoSciences Institute at Berkeley and Berkeley Global Science Institute , Berkeley , California 94720 , United States.
研究人员通过修改共价有机框架 (COF) 实现了多步固态合成. 这一过程产生了新的循环碳酸盐和硫酸盐连接,以前通过直接合成无法获得.
科学领域:
- 材料科学
- 有机化学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 是晶体多孔聚合物.
- 合成后修改 (PSM) 允许预先形成的框架的功能化.
- 在COF中常见的伊胺结合是很难修改的.
研究的目的:
- 展示使用COF的第一个多步固态有机合成.
- 通过PSM创建新的循环碳酸盐和硫酸盐连接.
- 调查PSM对COF结构,结晶性和多孔性的影响.
主要方法:
- 固态多阶段合成后修改一种因胺结合的COF (COF-170).
- 使用15N多CP-MASNMR光谱进行表征.
- 使用光谱数据分析结构和形状变化.
主要成果:
- 成功地将COF-170转化为循环碳酸盐和碳酸盐结合的框架.
- 通过新合成无法实现的新联系.
- 在COF中的PSM反应和氨基缺陷位点的量化产量.
- 观察到影响COF特性的显著形状和结构变化.
结论:
- 多步固态PSM是创建新型COF结构的可行策略.
- 非共价相互作用和形状灵活性对于COF结晶性和多孔性至关重要.
- 这项工作提升了固态合成的精度,使其达到溶液阶段的能力.
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