液态阶段的可调节的石墨烯纳米带超结构
Fugui Xu1, Chunyang Yu1, Alexander Tries2,3
1School of Chemistry and Chemical Engineering , Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University , 800 Dongchuan Road , Shanghai 200240 , China.
Journal of the American Chemical Society
|July 4, 2019
概括
我们用树突聚合物合成了石墨烯纳米带 (GNR), 这些GNR超结构显示了光电子应用的潜力.
科学领域:
- 材料科学
- 聚合物化学
- 纳米技术
背景情况:
- 石墨烯纳米丝带 (GNR) 是电子产品的有希望的材料.
- 控制GNR组装和属性对于应用至关重要.
- 状聚合物提供精确的结构控制.
研究的目的:
- 用树突聚合物合成功能化的石墨烯纳米带.
- 研究这些功能化的GNR的自组装行为.
- 探索由此产生的超结构的光电子特性.
主要方法:
- 精确定义的石墨烯纳米带 (GNR) 的合成.
- 用不同代的树突聚合物对GNR进行功能化.
- 使用光谱学和超快光导性的GNR超结构的表征.
主要成果:
- 在GNR上实现了0.59-0.68的接种比率.
- 在THF中证明了1D超分子自我组装成纳米线,螺旋和纳米纤维.
- 观察到近红外吸收 (650-700 nm) 和1.2-1.3 eV的光学带间隙.
- 螺旋结构表现出最长的自由载体 (3.5 psi) 和激子寿命 (数百 psi).
结论:
- 精确的3D树突结构可以实现可调的GNR自组装.
- 功能化的GNR形成有序的超结构,具有可调节的光电子特性.
- 这些GNR超结构具有先进光电子设备的潜力.
相关概念视频
Phase Diagrams
49.2K
A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
49.2K
Phase Transitions
22.8K
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
22.8K
Phase Transitions: Melting and Freezing
14.7K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
14.7K
Phase Transitions: Sublimation and Deposition
19.8K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
19.8K
Inductance: Single-Phase And Three-Phase Line
614
Understanding the inductance of transmission lines is crucial for efficient design and operation in electrical power systems. This discussion delves into the inductance characteristics of single-phase two-wire and three-phase three-wire transmission lines with equal phase spacing.
Single-Phase Two-Wire Line:
A single-phase line consists of two solid cylindrical conductors, denoted as x and y. Each conductor carries phasor currents ix and iy, respectively. Given that the sum of these currents is...
Single-Phase Two-Wire Line:
A single-phase line consists of two solid cylindrical conductors, denoted as x and y. Each conductor carries phasor currents ix and iy, respectively. Given that the sum of these currents is...
614
Capacitance: Single-Phase And Three-Phase Line
583
In electrical power systems, understanding the capacitance of transmission lines is fundamental for efficient operation.
Single-Phase Lines
Consider a single-phase, two-wire transmission line with equal phase spacing energized by a voltage source. One conductor carries a uniform positive charge, while the other carries an equal negative charge. The capacitance C of the line can be derived from the voltage V between the conductors. For a one-meter section of the line, the capacitance is given...
Single-Phase Lines
Consider a single-phase, two-wire transmission line with equal phase spacing energized by a voltage source. One conductor carries a uniform positive charge, while the other carries an equal negative charge. The capacitance C of the line can be derived from the voltage V between the conductors. For a one-meter section of the line, the capacitance is given...
583


