了解立方体多孔协调中的气体储存
Gregory R Lorzing, Aeri J Gosselin, Benjamin A Trump1
1Center for Neutron Research , National Institute of Standards and Technology , Gaithersburg , Maryland 20899 , United States.
Journal of the American Chemical Society
|July 5, 2019
概括
有孔的协调可以储存甲. 中子衍射揭示了内的特定吸附点,突出了它们适用于气体储存的应用.
科学领域:
- 材料科学
- 化学学
背景情况:
- 多孔分子固体对于气体的储存和分离至关重要.
- 结构数据有限, 阻碍了这些材料的优化.
- 协调为气体储存研究提供了一个有前途的平台.
研究的目的:
- 研究同结构协调的甲储存能力.
- 通过中子衍射阐明甲吸附点和相互作用.
- 评估这些材料的高压甲储存潜力.
主要方法:
- 综合和描述M24 (tBu-bdc) 24协调
- 在相关的M24 ((Me-bdc) 24 ((dabco) 6框架上进行中子衍射研究.
- 高压甲吸附测量
- 用于吸附点分析的分子建模.
主要成果:
- 多孔的BET表面面积高达1937m2/g,甲吸收高达143cm3/cm3.
- 甲吸附度在15至22kJ/mol之间.
- 中子衍射在窗和外表面发现了特定的吸附点,每共有56个位点.
结论:
- M24L24是有效的甲储存材料.
- 了解吸附点是优化气体储存能力的关键.
- 连接体功能化可以进一步增强外孔空间和存储性能.
相关概念视频
Coordination Number and Geometry
18.9K
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
18.9K
Coordination Compounds and Nomenclature
26.4K
In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
26.4K
Lattice Centering and Coordination Number
11.4K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
11.4K
Storage
372
A schema is a mental framework that helps individuals organize and interpret information. Schemata, formed from previous experiences, influence how we process new information: how we encode it, the inferences we make, and how we retrieve it. For instance, a schema for what a typical classroom looks like might include desks, a teacher's desk, a whiteboard, and students in such an environment. This expectation helps us quickly understand and navigate new classrooms without needing to analyze...
372
Understanding the Self
248
The self is a central aspect of human identity, encompassing an individual’s beliefs, emotions, perceptions, and experiences. It is a cognitive and psychological construct that enables individuals to interpret their traits and behaviors, influencing how they perceive themselves and interact with the world. While personality consists of stable and enduring characteristics, the self is shaped by self-perception and social experiences. This distinction highlights the dynamic nature of the...
248
Equations of Motion: Rectangular Coordinates and Cylindrical Coordinates
746
Understanding the motion of particles is a fundamental aspect of classical mechanics, and the choice of the coordinate system plays a pivotal role in unraveling the complexities of their dynamics.
When a particle moves relative to an inertial frame, the equations of motion can be expressed using rectangular components. If the motion is confined to the x-y plane, the equations having the x and y coordinates only can be used to simplify the mathematical representation.
However, when particles...
When a particle moves relative to an inertial frame, the equations of motion can be expressed using rectangular components. If the motion is confined to the x-y plane, the equations having the x and y coordinates only can be used to simplify the mathematical representation.
However, when particles...
746


