多元共价有机框架的网状合成
Bing Zhang1, Haiyan Mao2, Roc Matheu1
1Department of Chemistry , University of California-Berkeley ; Materials Sciences Division, Lawrence Berkeley National Laboratory; Kavli Energy NanoSciences Institute at Berkeley, and Berkeley Global Science Institute, Berkeley , California 94720 , United States.
Journal of the American Chemical Society
|July 6, 2019
概括
研究人员开发了一个复杂的二维多孔共价有机框架 (COF-346),具有新的拓. 这种先进材料的结构复杂度高于之前报告的COF.
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 是晶体多孔聚合物.
- 现有的二维COF拓相对简单.
- 开发具有复杂拓的COF是一个挑战.
研究的目的:
- 合成和描述一个新的2D多孔共价有机框架 (COF-346),具有前所未有的th拓.
- 探索具有复杂网络架构的COF的结构复杂性和潜力.
- 报告具有罕见或缺陷拓的额外COF.
主要方法:
- 使用六氨基烯,四氨基烯和1,3,5-三烯作为构建块.
- 用于构建框架的链接.
- 通过精确的链接器几何,计量和动态的磁体形成来实现成功的结晶.
主要成果:
- 成功合成了COF-346,一个具有新拓的二维多孔性共价有机框架.
- COF-346具有更高的结构复杂性,具有三种顶点和边缘,以及三种连接器.
- 报告了具有罕见kgd拓的COF-360和第一个具有缺陷tth拓的晶体多孔COF-340.
结论:
- 连接器的精确设计和动态 imine 化学对于构建复杂的 COF 架构至关重要.
- 在COF的结构多样性和复杂性方面,COF-346是一个显著的进步.
- 报告的COF扩展了已知的拓库,并为进一步的材料开发提供了平台.
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