原子薄金属硫化物
Lenore Kubie1, Marissa S Martinez1,2, Elisa M Miller1
1Chemistry and Nanoscience Center , National Renewable Energy Laboratory , Golden , Colorado 80401 , United States.
Journal of the American Chemical Society
|July 6, 2019
概括
研究人员开发了一种利用阴离子交换合成原子薄金属硫化物 (ATMS) 的新方法. 这些新的二维材料具有与传统形式不同的独特光学特性.
科学领域:
- 材料科学
- 纳米技术
- 固态化学
背景情况:
- 原子薄材料通常是像MoS2和石墨烯这样的层次结构.
- 不分层的散装材料缺乏生产二维形式的确立方法.
研究的目的:
- 开发非层层的原子薄金属硫化物 (ATMS) 的合合成方法.
- 探索这些新奇的二维材料的特性.
主要方法:
- 通过阴离子交换反应进行体合成.
- 使用单层和多层硫化银 (Ag2S) 作为前体.
- 使用Z型和L型连接物稳定合成的ATMS.
主要成果:
- 通过离子交换成功合成单层和少层ZnS,CdS,CoS2和PbS.
- 合成的ATMS保持大小和形状,侧面尺寸为5-10nm.
- 与血小板或量子点形式相比,在合成的ATMS中观察到不同的光学特性.
结论:
- 阴离子交换方法可以产生非分层的ATMS.
- 这些新的二维材料为潜在的应用提供了独特的光学特性.
- 合成方法扩展了可访问的二维材料库,超出了传统的分层化合物.
更多相关视频
08:43Separation of Uranium and Thorium for 230Th-U Dating of Submarine Hydrothermal Sulfides
Published on: May 20, 2019
7.2K
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
4.2K
相关概念视频
Metallic Solids
20.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Bonding in Metals
52.1K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
52.1K
Alkali Metals
24.2K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
24.2K
Metal-Ligand Bonds
24.1K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.1K
Properties of Transition Metals
29.7K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
29.7K
Preparation and Reactions of Sulfides
5.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.8K
