超分子网络与共价有机框架之间的电场介导可逆转换
Zhen-Feng Cai1, Gaolei Zhan1, Lakshya Daukiya1
1Department of Chemistry, Division of Molecular Imaging and Photonics , KU Leuven , Celestijnenlaan 200F , B-3001 Leuven , Belgium.
Journal of the American Chemical Society
|July 9, 2019
概括
导向电场精确地控制液体/固体界面上的酸凝结. 这使得分子网络和共价有机框架之间可以使用扫描道显微镜进行可逆切换.
科学领域:
- 表面科学
- 材料科学
- 纳米技术
背景情况:
- 酸可以在接口上自组装成有序结构.
- 控制酸的组合对于制造先进材料至关重要.
- 控制分子组合的现有方法可以在精度和范围上受到限制.
研究的目的:
- 研究用于控制酸凝结的定向电场.
- 探索自我组装分子网络和共价有机框架之间的相位过渡.
- 确定电场诱导的相变的可逆性.
主要方法:
- 使用带有定向电场的扫描道显微镜 (STM).
- 对液体/固体接口应用受控的电偏极性.
- 观察和分析由此产生的分子结构和相位过渡.
主要成果:
- 使用定向电场实现了酸凝结的局部控制.
- 应用偏差的极性决定了分子网络和共价有机框架之间的相变.
- 在环境条件下观察到的电场诱导的相变是可逆的.
结论:
- 定向电场提供了一个精确的方法来操纵分子在接口上的自组.
- 可逆控制相位转换的能力为动态分子材料开辟了可能性.
- 这种技术有助于制造共价有机框架和相关的纳米结构.
相关概念视频
Network Covalent Solids
16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.1K
Electric Field
12.3K
Consider two point charges, each exerting Coulomb force on the other. It is possible to describe the Coulomb interaction via an intermediate step by defining a new physical quantity called the electric field.
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
12.3K
Determining Electric Field From Electric Potential
4.9K
The electric field and electric potential are related to each other. If the electric field at various points in the region of interest is known, it can be used to calculate the electric potential difference between any two points. Similarly, if the electric potential is known for various points, then it is possible to calculate the electric field.
In general, regardless of whether the electric field is uniform, it points in the direction of decreasing potential because the force on a positive...
In general, regardless of whether the electric field is uniform, it points in the direction of decreasing potential because the force on a positive...
4.9K
Finding Electric Potential From Electric Field
5.4K
For a system of charges, it is easy to calculate the system's potential because potential is a scalar quantity. However, in some instances where calculating the electric field is more straightforward than finding the potential, the electric field is used to calculate the system's potential. For a positive charge, the electric field is radially outward, and the potential is positive at any finite distance from the positive charge. In such an electric field, the motion away from the...
5.4K
Covalent Bonds
160.5K
Overview
160.5K
Electric Field Inside a Conductor
7.3K
When a conductor is placed in an external electric field, the free charges in the conductor redistribute and very quickly reach electrostatic equilibrium. The resulting charge distribution and its electric field have many interesting properties, which can be investigated with the help of Gauss's law.
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
7.3K


