通过黄金对Enynes进行选择性折叠 (I) 具有远程C2Chiral元素的催化剂

Giuseppe Zuccarello1,2, Joan G Mayans1,2, Imma Escofet1,2

  • 1Institute of Chemical Research of Catalonia (ICIQ) , Barcelona Institute of Science and Technology , Av. Països Catalans 16 , 43007 Tarragona , Spain.

概括

新的黄金 (I) 催化剂能够对1,6-类进行选择性循环. 这些催化剂被用于首次对carexane天然产品的总合成,通过基质折叠来证明对立体化学的控制.

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