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相关概念视频

Ionic Radii03:10

Ionic Radii

33.3K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
33.3K
Ionic Bonds00:42

Ionic Bonds

129.4K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
129.4K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

20.0K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.0K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

68.1K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
68.1K
Ionic Crystal Structures02:42

Ionic Crystal Structures

16.9K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.9K
Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

86.2K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
86.2K

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相关实验视频

Updated: Jan 22, 2026

Flash Infrared Annealing for Perovskite Solar Cell Processing
05:15

Flash Infrared Annealing for Perovskite Solar Cell Processing

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使用离子液添加剂的平面矿太阳能电池具有长期稳定性

Sai Bai1,2, Peimei Da3, Cheng Li4,5

  • 1Clarendon Laboratory, University of Oxford, Oxford, UK. sai.bai@liu.se.

Nature
|July 12, 2019
PubMed
概括

离子液体提高了矿太阳能电池的效率和长期稳定性. 这些改进的太阳能电池在长时间的恶劣条件下表现出最小的性能退化,为可靠的矿光伏技术铺平了道路.

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Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
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Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance
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Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance

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科学领域:

  • 材料科学
  • 可再生能源
  • 太阳能发电

背景情况:

  • 金属化太阳能电池是一个非常有前途的光伏技术.
  • 虽然长期稳定性有所改善,但离子迁移仍然是一个关键的挑战,特别是在操作压力 (热量和光线) 下.

研究的目的:

  • 提高矿太阳能电池的效率和长期运行稳定性.
  • 解决矿活性层中持续存在的离子迁移问题.

主要方法:

  • 加入离子液体到矿膜中.
  • 阳性内在阴性 (PIN) 光伏设备的制造
  • 在高温 (70-75°C) 的持续模拟全谱阳光下测试装置的稳定性.

主要成果:

  • 包含离子液体的设备显示效率提高.
  • 长期稳定性的显著改善.
  • 最稳定的封装设备在恶劣条件下连续运行1800小时后仅有5%的性能下降.
  • 预计80%的性能保留的运行寿命约为5200小时.

结论:

  • 加入离子液体是提高矿太阳能电池效率和稳定的有效策略.
  • 这种方法显著减轻了离子迁移问题,从而提高了设备的寿命.
  • 在极端条件下的长期运行稳定性是可靠的矿光伏技术的关键进展.