通过层层的异离子模板组装的异离子聚合物
Qi Zheng1, Manuel Kupper1, Weimin Xuan1
1School of Chemistry , The University of Glasgow , Glasgow G12 8QQ , U.K.
Journal of the American Chemical Society
|July 12, 2019
概括
研究人员开发了一种新方法来合成具有多层的异构氧化活性聚氧甲酸盐 (POM). 由于其独特的混合金属和混合价值特性,这些新型POM具有先进电子材料的潜力.
科学领域:
- 无机化学
- 材料科学
- 纳米技术
背景情况:
- 在高面比结构和电子应用中,对异构氧化还原活性聚氧甲 (POMs) 的控制合成至关重要.
- 缺乏合成方法阻碍了这种POM集群的受控生长.
研究的目的:
- 开发一种可控合成多层异型POM的策略.
- 研究这些新型POM结构的自组装机制和特性.
主要方法:
- 异导向组装策略.
- 多层POM的合成成分为[W16Mo2O54(XO3) ]n−,[W21Mo3O75/76(XO3) 2) n−,和[W26Mo4O93(XO3) 3) n−.
- 分析技术以确认混合金属和混合价值状态.
主要成果:
- 一个由氧化还原活性金字塔异构离子模拟的10个多层异构POM的家族成功合成.
- 减少酸盐的引入对于自组装至关重要,从而产生混合金属 (W/Mo) 和混合价值 (WVI/MoV) POM.
- 多层POM由于混合度金属中心而表现出双极松.
结论:
- 开发的异导向组装策略使复杂POM架构的控制合成成为可能.
- 合成的POM具有适合电子材料的可调节电子特性.
- 这项工作为设计基于POM的功能性材料开辟了新的途径.
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