甲持续部分氧化为甲醇,由铜交换热质中的扩散配对铜二极管催化
Kimberly T Dinh1, Mark M Sullivan1, Karthik Narsimhan1
1Department of Chemical Engineering , Massachusetts Institute of Technology , 77 Massachusetts Avenue , Cambridge , Massachusetts 02139 , United States.
Journal of the American Chemical Society
|July 16, 2019
概括
使用特定的[Cu-O-Cu]二元活性位点,铜交换的化物催化甲转化为甲醇. 这一发现促进了选择性部分氧化催化,
科学领域:
- 催化剂
- 材料科学
- 化学工程
背景情况:
- 已知铜交换热石是甲部分氧化的催化剂.
- 负责选择性甲转化为甲醇的活性部位仍未确定.
- 了解活性位点对于优化催化剂性能至关重要.
研究的目的:
- 确定负责选择性甲部分氧化的特定活性位点.
- 阐明甲激活和甲醇形成的机制.
- 为设计更好的催化剂提供洞察力.
主要方法:
- 使用不同含量和铜载荷的SSZ-13化物.
- 使用氧气和水对甲氧化的反应机制进行了研究.
- 描述了石框架中存在的铜物种.
主要成果:
- 确定了一个[Cu-O-Cu]2+基因作为选择性甲转化的主要活性位点.
- 证明了化铜离子的质子辅助扩散促进了活性位点的形成.
- 已确定甲激活涉及确定速率的C-H裂变,随后以甲醇或完全氧化为CO2.
结论:
- 二度铜模是选择性甲部分氧化的关键.
- 优化焦化物特性 (高Al含量,低Cu负载) 和反应条件 (高CH4和H2部分压力) 提高了甲醇的选择性.
- 这项工作澄清了活性部位和机制,为先进的催化剂设计铺平了道路.
更多相关视频
06:52Positron Emission Tomography Using 64-Copper as a Tracer for the Study of Copper-Related Disorders
Published on: April 28, 2023
1.9K
09:35Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
12.1K
相关概念视频
Gas Exchange and Transport
76.6K
Gas exchange, the intake of molecular oxygen (O2) from the environment and the outflow of carbon dioxide (CO2) into the environment, is necessary for cellular function. Gas exchange during respiration occurs largely via the movement of gas molecules along pressure gradients. Gas travels from areas of higher partial pressure to areas of lower partial pressure. In mammals, gas exchange occurs in the alveoli of the lungs, which are adjacent to capillaries and share a membrane with them.
76.6K
Diffusion
216.8K
Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
216.8K
VSEPR Theory and the Effect of Lone Pairs
52.8K
Effect of Lone Pairs of Electrons on Molecule Geometry
52.8K
Pyruvate Oxidation
168.5K
After glycolysis, the charged pyruvate molecules enter the mitochondria via active transport and undergo three enzymatic reactions. These reactions ensure that pyruvate can enter the next metabolic pathway so that energy stored in the pyruvate molecules can be harnessed by the cells.
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
168.5K
Oxidation Numbers
42.2K
In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
42.2K
Social Exchange Theory
39.5K
We have discussed why we form relationships, what attracts us to others, and different types of love. But what determines whether we are satisfied with and stay in a relationship? One theory that provides an explanation is social exchange theory. According to social exchange theory, we act as naïve economists in keeping a tally of the ratio of costs and benefits of forming and maintaining a relationship with others (Rusbult & Van Lange, 2003).
39.5K
