有效的单原子铜装饰碳膜的可扩展生产
Hengpan Yang1, Yu Wu2, Guodong Li2
1Shenzhen Key Laboratory for Functional Polymer, College of Chemistry and Environmental Engineering , Shenzhen University , Shenzhen , Guangdong 518060 , China.
Journal of the American Chemical Society
|July 27, 2019
概括
研究人员在碳纳米纤维上开发了新的铜单原子催化剂,以有效地减少二氧化碳 (CO2RR). 这种催化剂可产生具有显著稳定的高价值甲醇,为二氧化碳转化提供了有前途的解决方案.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 电催化减少二氧化碳 (CO2RR) 对减轻环境问题至关重要.
- 开发有效的催化剂将二氧化碳转化为甲醇等有价值的产品仍然是一个重大挑战.
研究的目的:
- 在穿孔碳纳米纤维 (CuSAs/TCNFs) 上装饰的单个铜原子的合成和特征.
- 评估CuSA/TCNF作为CO2RR的自支阴极的性能.
- 通过DFT计算研究甲醇生产的机制.
主要方法:
- 用于大规模生产CuSA/TCNF的简单合成策略.
- 作为液态相中的二氧化碳RR的阴极的CuSA/TCNF膜的电催化试验.
- 密度函数理论 (DFT) 计算以了解催化机制.
主要成果:
- CuSA/TCNF表现出优异的机械性能,并直接作为一个阴极.
- 几乎纯粹的甲醇产生了44%的法拉第效率.
- 在C1产品中实现了超过50小时的部分电流密度为-93 mA cm-2.
- DFT计算表明Cu单个原子有利于*CO中间体的降解为甲醇.
结论:
- CuSAs/TCNFs膜是一种高效且稳定的CO2RR催化剂,产生甲醇.
- 通过孔结构和单个原子是催化剂性能的关键.
- 这项工作为设计用于电催化应用的先进单原子催化剂提供了洞察力.
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