对超分子聚合物的动力稳定性的拓影响
Atsuhito Suzuki1, Keisuke Aratsu1, Sougata Datta2
1Division of Advanced Science and Engineering, Graduate School of Engineering , Chiba University , 1-33 Yayoi-cho, Inage-ku , Chiba 263-8522 , Japan.
Journal of the American Chemical Society
|July 27, 2019
概括
超分子聚合物的拓差异显著影响其动力稳定性. 循环聚合物比开放式聚合物具有更大的稳定性,使控制的转化成为热力学结构.
科学领域:
- 超分子化学
- 聚合物科学
- 材料科学
背景情况:
- 超稳定分子组合在高分子聚合物研究中至关重要.
- 区分类似的超分子图案的动态稳定性是一项挑战.
- 拓变化可以影响组装动态.
研究的目的:
- 研究超分子聚合物的拓效应.
- 为了区分循环和开放的超分子聚合物之间的动力稳定性.
- 探索控制的转化到热力学稳定的结构.
主要方法:
- 在非极性溶剂中形成含亚博的单体混合物.
- 用热处理来诱导运动和热力学组件的形成.
- 原子力显微镜 (AFM) 用于分子组件的直接可视化.
- 照片诱导的结构变化探测器的动力稳定性.
主要成果:
- 形成了具有循环和开放拓的超分子聚合物的动态复杂混合物.
- 在进一步加热后获得了热力学稳定的扭曲纤维.
- 与开放式相比,循环的高分子聚合物表现出较高的动力稳定性.
- 光诱导开放成功地将转移稳定的循环物种转化为热力学结构.
结论:
- 拓学在确定转移稳定的超分子聚合物的动力稳定性方面发挥着关键作用.
- 循环结构中没有聚合端子,提高了它们的动力稳定性.
- 控制的光诱导转化提供了操纵超分子聚合物的途径.
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