基于乙酸的二维轻化物纳米材料 (F-Ln,Ln = La,Ce,Pr和Nd):形态,结构,生长机制和稳定性
Leitao Zhang1, Weimin Kang1, Qiang Ma1
1State Key Laboratory of Separation Membranes and Membrane Processes , Tianjin Polytechnic University , Tianjin 300387 , China.
Journal of the American Chemical Society
|July 31, 2019
概括
研究人员开发了一种新的,简单的方法,以创建基于二维酸的轻化 (F-Ln) 纳米材料. 这些超薄,缺陷丰富的材料显示出极大的稳定性和催化和能源应用的潜力.
科学领域:
- 材料科学
- 纳米技术
- 无机化学
背景情况:
- 发现新的二维 (2D) 材料至关重要,但很困难.
- 现有的二维材料合成方法往往复杂且耗费大量能量.
研究的目的:
- 开发一种简单的自下而上的方法,用于制造基于二维酸盐的轻化 (F-Ln) 纳米材料.
- 描述合成的F-Ln材料的形态,微观结构和结构.
- 研究新型二维纳米材料的生长机制和稳定性.
主要方法:
- 在室温和大气压力下进行自下而上的合成.
- 使用各种特征技术,包括电子显微镜和X射线衍射.
- 通过反应动力学和中间分析研究生长机制.
主要成果:
- 成功合成了厚度低至1.45纳米的超薄2D F-Ln纳米材料 (La,Ce,Pr,Nd).
- 描述F-Ln为含有缺陷的纳米材料,由10nm以下的纳米晶域组成.
- 确定了F-Ce作为BN类F-Ce和酸的交替层的结构.
- 确定了三阶段的生长机制,包括水解,离子诱导的转化和离子引导的组装.
- 证明了极好的环境稳定性 (空气,热,溶剂,电子束).
结论:
- 建立了一个简单的,室温,大气压方法来合成新的2D F-Ln纳米材料.
- 合成的F-Ln材料具有独特的缺陷丰富的结构和出色的稳定性.
- 这些发现扩大了二维材料的库,并为催化,吸附,分离和能量储存/转化提供了应用潜力.
相关概念视频
Stability of structures
491
In mechanical engineering, the stability of systems under various forces is critical for designing durable and efficient structures. One fundamental way to explore these concepts is by analyzing systems like two rods connected at a pivot point, O, with a torsional spring of spring constant k at the pivot point. This system is similar in appearance to a scissor jack used to change tires on a car. In this case, the arms of the linkage (equivalent to the rods in this system) are entirely vertical,...
491
Radical Chain-Growth Polymerization: Mechanism
3.4K
The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this species into...
3.4K
Anionic Chain-Growth Polymerization: Mechanism
2.5K
The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael...
2.5K
Cationic Chain-Growth Polymerization: Mechanism
2.8K
The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
2.8K
RNA Stability
35.6K
Intact DNA strands can be found in fossils, while scientists sometimes struggle to keep RNA intact under laboratory conditions. The structural variations between RNA and DNA underlie the differences in their stability and longevity. Because DNA is double-stranded, it is inherently more stable. The single-stranded structure of RNA is less stable but also more flexible and can form weak internal bonds. Additionally, most RNAs in the cell are relatively short, while DNA can be up to 250 million...
35.6K
Photoreceptors and Plant Responses to Light
28.3K
Light plays a significant role in regulating the growth and development of plants. In addition to providing energy for photosynthesis, light provides other important cues to regulate a range of developmental and physiological responses in plants.
28.3K


