高性能透明导体的快速电化学清洗银纳米线薄膜
Yongjie Ge1, Jianfang Liu1, Xiaojun Liu1
1State Key Laboratory for Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering , Hunan University , Changsha 410082 , China.
Journal of the American Chemical Society
|July 31, 2019
概括
一种新的电化学清洗方法快速从银纳米线 (Ag-NW) 薄膜中去除聚烯 (PVP) 连接物. 这一过程显著提高了载体传输,提高了光电子设备的导电性和性能.
科学领域:
- 材料科学
- 电化学
- 纳米技术
背景情况:
- 银纳米线 (Ag-NW) 薄膜对于透明导体来说是有前途的.
- 剩余的聚烯 (PVP) 连接物阻碍它们的载体运输特性.
研究的目的:
- 开发一种快速的电化学清洗策略,以从Ag-NW表面中去除PVP连接物.
- 显著提高Ag-NW薄膜的载体传输性能,而不会影响传导能力.
主要方法:
- 在吸附/演化模式附近应用负电化学电位.
- 在5-15秒内实现有效的PVP连接物移位.
- 在Ag-NW/Ag-NW连接点和Ag-NW薄膜/活性层连接点创建了超清洁的接口.
主要成果:
- Ag-NW薄膜的薄膜阻力从49到13欧姆/平方 (在550nm保持90.91%的透射率).
- 在Ag-NW薄膜/活性层接口上降低了94.3%.
- 在可穿戴式应变传感器中提高灵敏度,并在叠加的光电子设备中提高电流收集效率.
结论:
- 电化学清洗对于从Ag-NW中去除表面连接物非常有效.
- 这种方法大大改善了飞机内和飞机外的载体运输.
- 这种方法促进了Ag-NW薄膜在电子和光电子领域的更广泛应用.
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