关于"模仿过渡金属的土复合物 M ((CO) 8 (M = Ca,Sr或Ba) 的观察"的评论
Lili Zhao1, Sudip Pan1,2, Mingfei Zhou3
1Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China.
Science (New York, N.Y.)
|August 10, 2019
概括
我们否认 (Ca) 不像Ca (CO) 8中的过渡金属那样结合. 我们的分析表明他们的结论源于对粘合模型和量子化学方法的误解.
科学领域:
- 无机化学
- 量子化学
背景情况:
- 最近的一篇评论质疑 (Ca) 在Ca (CO) 8中与过渡金属类似的结合.
- 这一说法依赖于化学结合理论的具体解释.
研究的目的:
- 驳斥了Ca在Ca (CO) 8中没有呈现过渡金属类结合的说法.
- 解决粘合模型和量子化学分析中所谓的误解.
主要方法:
- 重新评估已建立的结合模式.
- 对量子化学方法的应用和解释进行批判性分析.
主要成果:
- 兰迪斯和其他人的说法. 是基于对结合原则的错误理解.
- 发现了量子化学数据的错误应用和错误解释.
结论:
- 在Ca (CO) 8中 (Ca) 的结合与过渡金属的特性一致.
- 该批评强调了准确的结合模型应用和量子化学解释的重要性.
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