在金属有机框架内生成和稳定小集群
Kathrin Kratzl1, Tim Kratky1, Sebastian Günther1
1Catalysis Research Center , Technical University of Munich , Garching 85748 , Germany.
Journal of the American Chemical Society
|August 11, 2019
概括
本研究提出了一种使用金属有机框架稳定小纳米集群 (PtNC) 的新方法. 由此产生的PtNCs@ZIF-8复合材料是稳定的,适用于催化,特别是氧降解反应.
科学领域:
- 材料科学
- 纳米技术
- 催化剂
背景情况:
- 无联体纳米集群 (PtNC) 对于催化至关重要,但难以稳定.
- 原子精确集群具有独特的特性,但需要保护矩阵来实现实际应用.
研究的目的:
- 开发一种产生和稳定无体的小纳米集群 (PtNCs) 的方法.
- 创建一个用于存储和处理这些PtNC的复合材料.
- 评估衍生PtNC在电催化应用中的潜力.
主要方法:
- 基尼集群的封装在地质化伊米达酸框架ZIF-8内.
- 通过热脱碳生成PtNCs@ZIF-8复合物.
- 使用UV/vis,IR光谱,HR-TEM,HAADF-STEM,XPS和PXRD进行表征.
- 用酸去除ZIF-8矩阵并转移到碳基板.
主要成果:
- 在ZIF-8中成功合成空气稳定的Pt12±纳米集群,具有受控的Pt负荷 (1-20%).
- 在高温回火和催化化过程中,PtNC 保持其大小.
- 衍生Pt纳米粒子 (1.14 ± 0.35 nm) 在氧降解反应 (ORR) 中表现出高性能.
结论:
- 金属有机框架模板方法有效地稳定小纳米集群.
- PtNCs@ZIF-8复合材料是用于PtNC存储和处理的多功能平台.
- 这些纳米颗粒显示出高效的电催化氧降解的潜力.
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