在最富的酸中具有快速的离子导电性Li14SiP6
Stefan Strangmüller1, Henrik Eickhoff1, David Müller1
1Department of Chemistry , Technische Universität München , Lichtenbergstrasse 4 , D-85747 Garching , Germany.
Journal of the American Chemical Society
|August 13, 2019
概括
研究人员开发了一种全固态电池的新固体电解质. 这种"富"的酸材料具有超离子导电性,为先进的电池技术铺平了道路.
科学领域:
- 材料科学
- 固态化学
- 电化学
背景情况:
- 所有固态电池需要具有高离子导电性的固体电解质来安全有效地储存能量.
- 现有的固体电解质在实现高导电性和稳定性方面面临挑战.
- 酸三甲酸是固体电解质的一类有前途的材料.
研究的目的:
- 合成和描述一种新的"富"酸固体电解质.
- 研究这种新材料中的离子导电性和离子传输机制.
- 为潜在的电池应用扩大酸特酸盐的家族.
主要方法:
- 球磨合成,然后进行热处理以获得晶体材料.
- 温度依赖的粉末中子衍射和DFT计算以分析扩散路径.
- 最大法,阻抗光谱和7Li NMR光谱研究离子的移动性.
主要成果:
- 合成了一种具有3D导电通路的新型晶体"丰富"酸盐.
- 这种材料在室温下表现出超离子导电性 (σ > 10^-3 S cm^-1),活性能量低 (30-32 kJ mol^-1).
- 分析显示通过四面体和八面体空隙扩散,由不规则的Li/Si占用促进.
结论:
- 开发的"富"酸是全固态电池的有前途的固体电解质.
- 该材料的结构和组成使其具有高离子导电性和移动性.
- 这项工作有助于推进下一代储能固体电解质材料的发展.
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