一个铁双原子催化剂用于氧气演化反应
Lichen Bai1, Chia-Shuo Hsu2, Duncan T L Alexander3,4
1Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering , Ecole Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-LSCI , BCH 3305 , CH 1015 Lausanne , Switzerland.
Journal of the American Chemical Society
|August 17, 2019
概括
单原子催化剂可以转化为高效的双原子催化剂,用于氧化演化反应 (OER). 这种新的 Co-Fe 催化剂表现出卓越的性能,证明了双原子催化的潜力.
科学领域:
- 材料科学
- 催化剂
- 电化学
背景情况:
- 单原子催化剂具有高原子效率,但在需要双金属促进的反应中是有限的,例如氧演化反应 (OER).
- 氧化演化反应 (OER) 对于能量转化至关重要,但需要高效和稳定的催化剂.
研究的目的:
- 通过将单原子催化剂转化为双原子催化剂,为氧化演化反应 (OER) 开发一种高度活性和稳定的催化剂.
- 研究新型双原子催化剂的活性部位结构和催化机制.
主要方法:
- 在现场将单原子 (Co) 预催化剂转化为-铁 (Co-Fe) 双原子催化剂.
- 电化学测量,包括操作式X射线吸收光谱 (XAS),显微镜和光谱,以描述催化剂及其性能.
主要成果:
- 在现场转换的Co-Fe双原子催化剂显示了OER在金属氧化物中最高的转换频率之一.
- 运行XAS和其他表征技术确定了二极体Co-Fe部分作为负责增强催化活性的活性部位.
结论:
- 双原子催化是设计高效且明确的氧化演化反应 (OER) 的有希望的策略.
- 开发的Co-Fe双原子催化剂代表了OER催化学的重大进步,为能量转换技术提供了新的途径.
相关概念视频
The Evidence for Evolution
47.7K
Genetic variations accumulating within populations over generations give rise to biological evolution. Evolutionary changes can result in the formation of novel varieties and entire new species. These changes are responsible for the diverse forms of life inhabiting the planet. The evidence for evolution suggests that all living organisms descended from common ancestors.
47.7K
The Atomic Theory of Matter
126.9K
The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers. Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, meaning “indivisible.” Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements” — fire, earth, air, and water — and could be infinitely divided. Interestingly, these philosophers...
126.9K
Convergent Evolution
31.4K
Evolution shapes the features of organisms over time, ensuring that they are suited for the environments in which they live. Sometimes, selection pressure leads to the rise of similar but unrelated adaptations in organisms with no recent common ancestors, a process known as convergent evolution.
31.4K
Atomic Structure
207.1K
Overview
207.1K
Acids, Bases and Neutralization Reactions
63.6K
An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to numerous natural and technological processes, ranging from the chemical transformations within cells or lakes and oceans to the industrial-scale production of fertilizers, pharmaceuticals, and other substances essential to the society.
63.6K
Half-life of a Reaction
38.7K
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of the remaining concentration of the reactant is consumed. For example, during the decomposition of hydrogen peroxide, during the first half-life (from 0.00 hours to 6.00 hours), the concentration of H2O2 decreases from 1.000 M to 0.500 M. During the second half-life (from 6.00 hours to 12.00 hours), the concentration decreases from 0.500 M to...
38.7K


