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相关概念视频

Competition02:34

Competition

24.3K
When organisms require the same limited resources within an environment, they may have to compete for them. Competition is a net-negative interaction. Even if two competing individuals or populations do not interact directly, the overall fitness of both competitors is lowered as a result of not having full access to the limited resource.
24.3K
The Nitrogen Cycle01:49

The Nitrogen Cycle

59.6K
Nitrogen atoms, present in all proteins and DNA, are recycled between abiotic and biotic components of the ecosystem. However, the primary form of nitrogen on Earth is nitrogen gas, which cannot be used by most animals and plants. Thus, nitrogen gas must first be converted into a usable form by nitrogen-fixing bacteria before it can be cycled through other living organisms. The use of nitrogen-containing fertilizers and animal waste products in human agriculture has greatly influenced the...
59.6K
Overview of Nitrogen Metabolism01:20

Overview of Nitrogen Metabolism

11.0K
Nitrogen is a very important element for life because it is a major constituent of proteins and nucleic acids. It is a macronutrient, and in nature, it is recycled from organic compounds and stored in the form of  ammonia, ammonium ions, nitrate, nitrite, or  nitrogen gas by many metabolic processes. Many of these metabolic processes are carried out only by prokaryotes.
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
11.0K
The Carbon Cycle01:14

The Carbon Cycle

43.3K
Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
43.3K
Carbon Skeletons01:12

Carbon Skeletons

114.2K
Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side...
114.2K
Inorganic Nitrogen Assimilation01:22

Inorganic Nitrogen Assimilation

489
Nitrogen is an essential element in biological systems, forming a crucial component of proteins, nucleic acids, and other cellular constituents. Many bacteria and archaea acquire nitrogen in the form of nitrate (NO₃⁻) or ammonia (NH₃), which are then assimilated into biomolecules through specific enzymatic pathways.Assimilatory Nitrate ReductionWhen nitrate enters the cell, it undergoes a two-step reduction process known as assimilatory nitrate reduction. Initially, the enzyme...
489

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Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge
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Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge

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竞争性气与碳道

Cláudio M Nunes1, André K Eckhardt2, Igor Reva1

  • 1CQC, Department of Chemistry , University of Coimbra , 3004-535 Coimbra , Portugal.

Journal of the American Chemical Society
|August 20, 2019
PubMed
概括

碳和的重原子量子力学道 (QMT) 比以前认为的更为常见. 这项研究表明这些QMT途径可以相互竞争,从同一分子中产生不同的产物.

科学领域:

  • 物理化学
  • 量子化学
  • 化学动力学

背景情况:

  • 重原子量子力学道 (QMT) 在历史上被认为是不可能的.
  • 最近的发现表明重原子QMT比预期的更频繁.

研究的目的:

  • 调查碳与重原子QMT的竞争性.
  • 通过竞争的 QMT 途径从相同的原料中产生不同的产品.

主要方法:

  • 在冷温度 (3-18K) 中在固体中生成氨基替代的benzazirine.
  • 在黑暗中监测自发衰变并确定反应半衰期.
  • 使用量子化学计算来分析反应路径.

主要成果:

  • 观察到氨基替代品benzazirine的自发衰变,其半衰期为210分钟.
  • 确定了两个不同的产品:p-aminophenylnitrene和氨基替代基因胺.
  • 发现反应速率与温度无关,这与经典的过渡状态理论相矛盾.
  • 量子化学计算证实了两个竞争的碳与QMT路径.

结论:

  • 碳和重原子QMT可以具有竞争力,从单个前体产生多种产品.

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  • 温度独立的反应速率突出了量子力学效应的经典预测.
  • 这项研究强调了量子现象在化学反应和分子行为中的重要作用.