具有超强机械性质的交融液晶聚氨/聚烯酸弹性体
Hai-Feng Lu1, Meng Wang1, Xu-Man Chen1
1School of Chemistry and Chemical Engineering, Jiangsu Province Hi-Tech Key Laboratory for Bio-medical Research, State Key Laboratory of Bioelectronics, Institute of Advanced Materials , Southeast University , Nanjing 211189 , China.
Journal of the American Chemical Society
|August 21, 2019
概括
新的相互透的液晶弹性体 (LCE) 材料具有超强的执行能力,克服了以前的限制. 这种LCE机械的突破可以为软执行器提供广泛的工业应用.
科学领域:
- 聚合物科学与工程
- 材料科学
- 软机器人
背景情况:
- 液晶弹性体 (LCE) 已经研究了几十年,但由于适度的执行力,缺乏工业应用.
- 主要限制源于液晶 (LC) 到同位素相位过渡过程中产生的力,这是一个关键的启动时刻.
研究的目的:
- 开发一种具有显著增强执行力学特性的新型LCE材料.
- 通过提高其机械性能来解决基于LCE的软执行器的工业应用缺口.
主要方法:
- 合成了一种相互透的聚合物网络 (IPN),其中包括主链聚氨LCE和液晶聚烯酸热固体.
- 同时聚合两个网络以创建双网络结构.
- 材料的形状记忆行为,收缩率,执行应力,工作能力和热刺激下的机械强度.
主要成果:
- 在140°C达到86%的最大收缩率,超过了典型的LC到同位素相位过渡.
- 证明了超强的执行力学:执行阻塞应力 (2.53 MPa),工作能力 (1267.7 kJ/m3),断裂强度 (7.9 MPa) 和弹性模量 (10.4 MPa).
- 这种材料具有非凡的承载能力,
结论:
- 开发的相互透的聚合物网络-LCE材料具有前所未有的机械性能和双向形状记忆能力.
- 这些卓越的性能克服了LCE执行力的先前限制,为基于LCE的软执行器的实用工业应用铺平了道路.
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